The-paint-and-coating--MSDS-English英文油漆涂料物质安全资料表.docx

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1、Safety specificationMSDS of paint and coatingPart 1 chemical and enterprise identificationChinese name of chemicals含易燃溶剂的合成树脂、油漆、辅助材料、涂料等制品闭杯闪点W60CEnglish nameSynthetic resins, auxiliary materials, paints and other products containing flammable solvent (flash point not more than 60)Registration numb

2、erofhazardous chemicals catalogue2828Part 2 composition / informationPureMixture VConcentration of main harmfulcomponentsCAS No1, 3-xylene108-38-31, 4-xylene106-42-31, 2-xylene95-47-6Butanol71-36-3Methyl isobutyl ketone108-10-1Color pasteW 5% (mass percentage)7429-90-5Volatile organic compounds (VOC

3、) W 870 g / LPart 3 overview of riskRisk category(1) Flash point 23 and initial boiling point W 35 :Flammable liquids, class 1(2) Flash point 35 :Flammable liquids, class 2(3) 23 W flash point 60 :Flammable liquids, class 3Health hazards and environmental hazards need to be judged according to the c

4、omponents.Invasion routeInhalation, ingestion and skin absorptionHealth hazardsContact or use of this product is harmful to human body. Its steam can stimulate eyes, mucous membrane, upper respiratory tract and skin, and has anesthetic effect on central nervous system. Long term exposure or shortter

5、m inhalation of high concentration steam can cause dizziness, headache, nausea, vomiting, loss of appetite, chest tightness, weakness of limbs, burning pain, dry skin, chapped skin and skin diseases. Can cause acute poisoning.EnvironmentalhazardsThis product is harmful to the environment, mainly ref

6、lected in the water and air pollution, should pay special attention to the water pollution.Explosion hazardThis product is easy to cause combustion in case of open fire and high heat, and the steam and air are easy to form explosive mixture.Part 4 first aid measuresSkin contactTake off contaminated

7、clothes and wash skin thoroughly with soap and waterEye contactImmediately clean eyes and rinse with plenty of water. Seek medical adviceInhalationLeave the scene quickly and go to fresh air.In case of dyspnea, give oxygen; if breathing stops, perform artificial respiration.Seek medical adviceIngest

8、ionRinse mouth, drink water and stomach immediately. Seek medical advicePart 5 fire fighting measuresHazardcharacteristicsThis product is easy to cause combustion in case of open fire and high heat; its steam and air form an explosive mixture, which can cause combustion and explosion in case of open

9、 fire and high heat. Strong reaction with oxidant will cause combustion and explosion. Steam is heavier than air and can spread to a considerable distance at a lower place, and it is easy to ignite when encountering fire source. In case of high heat, the internal pressure of the container containing

10、 the product will increase, which may cause cracking and explosion. If the flow rate is too fast, it is easy to generate and accumulate static electricity.Harmful combustion productsWhen burning, there is smoke and produces carbon monoxide and carbon dioxide.Fire fighting method and fire extinguishe

11、rFirefighters must wear positive pressure respirators, wear whole body fire protective clothing, and try to put out fires at windward places, using dry powder, sand, foam and carbon dioxide to fight.Part 6 emergency treatment of leakageEmergencyManagementCut off the fire source, evacuate the irrelev

12、ant personnel from the leakage pollution area to the safe area, strictly restrict the access of personnel, find and cut off the leakage source, and prevent entering the sewer. It is recommended that the emergency treatment personnel wear positive pressure respirator and fire protection clothing. Sma

13、l1 amount of leakage: collect the overflow liquid into the covered container as far as possible, absorb the residual liquid with sand or other inert materials, and send the used adsorbate to the treatment site specified by the environmental sanitation department. Large amount of leakage: build a dik

14、eor dig a pit to collect it in a special container or transport it to the disposal site specified by the environmental sanitation department. Foam coverage is used to suppress evaporation to protect field personnel. Replace the leaking package.Part 7 handling and storageOperationThe operators must r

15、eceive special safety training and strictly abide byprecautionsthe safety operation regulations and relevant regulations of painting operation. To strengthen labor protection, it is suggested that the operators should wear various protective equipment, and the exposed skin should be coated with prot

16、ective cream. When the skin is stained with this product, it should be washed with soap in time. The area where the product is used shall have obvious “No Fireworks“ signs, no open fire, no spark producing mechanical equipment and tools, and sufficient fire-fighting equipment shall be set up. When u

17、sing this product, it should be well ventilated. In case of poor ventilation, forced ventilation should be used. All electrical equipment and lighting facilities in the area where the product is used shall be explosion-proof and anti-static accumulation shall be prevented. The faci1ities shal1 be gr

18、ounded and personnel shal1 wear anti-static work clothes. At the end of each use, the unused product should be covered and put back into the warehouse. It is strictly forbidden to put it in unattended places. The cotton yarn and dishcloth stained with this product must be concentrated in the iron bu

19、cket with cover, and it is forbidden to discard it at will. Pay attention to light loading and unloading to prevent package damage, and provide leakage emergency treatment equipment.StorageIt should be stored in a dry, cool, ventilated, clean warehouse with “NoprecautionsFireworks” signs. It should

20、be protected from direct sunlight and away from the heat source of fire. The temperature of the warehouse should not exceed 30 (spray water on the top of the warehouse can be used in high temperature season), and the relative humidity should not exceed 80%. Keep the container sealed. Do not store to

21、gether with oxidant, acid, alkali and edible chemicals. There should be enough fire fighting equipment in the warehouse. The storage place shall be equipped with lightning protection device, all electrical equipment and lighting facilities in the warehouse shall be explosion-proof, and the warehouse

22、 shall be equipped with leakage disposal facilities. Handle with care to prevent package damage.Part 8 exposure control / personal protectionMaximumallowable concentrationXylene (skin): lOOmg / m3; butanol: 200 mg / m3; methyl isobutyl ketone: no standardMonitoringmethodsDetermination of toxic gas c

23、oncentration in air by gas chromatographyengineeringcontrolStrengthen ventilationrespiratorysystem protectionWhen the concentration in the air exceeds the standard, it is recommended to wear a filter type gas mask (half mask). Wear positive pressure respirator during emergency rescue or evacuationEy

24、e protectionWear chemical resistant glassesPhysical protectionWear anti poison penetration work clothesHand protectionApply protective cream or wear oil resistant rubber glovesOther protectionSmoking, eating and drinking are prohibited at the work site. Avoid alcohol before work. After work, take a

25、shower and change clothes. Preemployment and regular physical examinationPart 9 physical and chemical propertiesAppearance and character: colorless or yellowish transparent uniform 1iquid with special fragrance.PH value:No data available*Melting point ()： -47. 9Boiling point ()： 139Relative density

26、(water = 1)： 0. 86*Relative vapor density (air = 1)： 3. 66*Saturated vapor pressure (kPa)： 1. 33 (28. 3 )*Heat of combustion (kJ / mol)： 4549. 5*Critical temperature (C)： 343. 9*Critical pressure (MPA)： 3. 54* Logarithm of octanol / water partition： 3. 2Flash point () ： 27Ignition temperature ()： 52

27、5* Upper explosion limit% (V / V)： 7. 0* Lower explosion limit% (V / V)： 1. 1Solubility: miscible with epoxy paint.Main uses: as h06-l epoxy zinc rich primer, 11103 epoxy micaceous iron antirust paint, 11172 epoxy topcoat and other epoxy paint application viscosity adjustment and cleaning agent for

28、epoxy paint coating construction.(* refers to the data of 1, 4 xylene, extracted from safety technology of hazardous chemicals)Part 10 stability and reactivityStability: stable.Prohibited substances: It is forbidden to store in the same storehouse with oxidant, acid and alkali.Conditions to avoid co

29、ntact: high heat, open fire.Polymerization hazard: cannot happenDecomposition products: carbon monoxide, carbon dioxide.Part 11 toxicological information* Acute toxicity: LD50 5000mg / kg (rat oral)LC50 19747mg / m3, 4 hours (rat inhalation)*Subacute and chronic toxicityResults: inhalation of 5000 m

30、g / m3, 8 hours / day, 55 days in rats and rabbits resulted in eye irritation, failure, ataxia, a slight decrease in RBC and WBC, bone marrow hyperplasia and 3% 一 4% megakaryocytes.*Irritant: human eyes: 200ppm, causing irritation. The rabbits were moderately stimulated with 500 mg (24 hours) of ski

31、n.Sensitization: no data available*Mutagenicity: no data available*Teratogenicity: The minimum toxic concentration (TCL) of 19 mg/m3 was inhaled in rats, which caused abnormal development of muscle bone marrow at 2 h (9-14 d).Carcinogenicity: no data available(* refers to the data of 1, 4 xylene, ex

32、tracted from safety technology of hazardous chemicals)Part 12 ecological informationEcotoxicity: no data availableBiodegradability: no data availableNon biodegradabi1ity: no data availablePart 13 waste disposalWaste property : hazardous wasteWaste disposal method: send to the disposal site designate

33、d by the environmental sanitation department or treat with controlled incineration method.Notes on Abandonment: the national and local environmental protection regulations should be referred to for waste storage and disposal.Part 14 transport informationDangerous goods No33648(not listed)UN number：1

34、992Packaging mark: flammable liquidPackaging category： IIIPacking method: inner packing: large opening steel bucket or large opening steel pail (with cover); outer packing: wooden case (wood board or wooden strip), corrugated box, bamboo basket, wicker basket or no outer packing.Transportation preca

35、utions: handle with care to prevent package and container damage. Transportation should be carried out in the morning and evening in summer to prevent sunlight exposure, and transport according to relevant regulations.Part 15 regulatory informationCatalogue of hazardous chemicals (2015 Edition)Classification and marking of common hazardous chemicals (GB 13690-2009) Occupational exposure limits for hazardous factors in Workplace (gbz2. 1-2007) Classification and code of dangerous goods (gb69442012) List of dangerous goods (gbl22682012)