新疆典型农业地区土壤中有机氯农药(OCPs)分布特征及风险评价.pdf

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1、新疆典型农业地区土壤中有机氯农药(OCPs)分布特征及风险评价冉聃鲁建江姚晓瑞刘子龙杜志坚张硕石河子大学化学化工学院,新疆兵团化工绿色过程重点实验室,石河子832003摘要:为加强有机氯农药(organic chlorinated pesticides,OCPs)的污染预防与控制,该研究分析了新疆典型农业地区有机氯农药的污染状况并对其进行了风险评价。采集表层土壤样品36个,分析其中15种OCPs的残留状况。六六六(Hexachlorocyclohexanes,HCHs)、滴滴涕(dichlorodiphenyltrichioroethanes,DDTs)、氯丹类化合物、硫丹和硫丹盐的质量分数范

2、围分别是0.3722.82、0.91858.47、0.1547.08 ng/g、N.D(未检出)16.27和N.D73.83 ng/g。对OCPs的来源进行分析,发现HCHs来源于历史上工业HCHs的使用或近期林丹的输入,DDT来源于工业品的违法使用和三氯杀螨醇的使用,研究区域氯丹存在新的来源,而硫丹新来源较少。通过主成分分析,从15种OCPs中提取了5个主成分,总方差解释量达到了79.93。5个主成分分别归因于DDT和工业HCH s的使用、OCPs原料的差异以及研究区域内病虫害的发病特征等。利用灰色关联分析研究区域内OCPs污染状况,结果表明石河子污染水平最高,各研究区域土壤均需要采取进一步

3、的污染控制措施。农业土壤;农药;分布特征;风险评价;有机氯;新疆10. 3969/j.issn. 1002-6819.2012.03.039X53A1002-6819(2012)-03-0225-052011-04-202011-11-18国家自然科学基金资助(20967007); EEPSEA-中国环境经济研究项目(20004801)资助冉聃(1987-),女,石河子石河子大学化学化工学院/新疆兵团化工绿色过程重点实验室,832003。Email: 鲁建江(1967-),男,副教授。石河子石河子大学化学化工学院/新疆兵团化工绿色过程重点实验室,832003。Email: ljj_万方数据峰面

4、万方数据质量万方数据1 Jones K C, Voogt P D. Persistent organic pollutants (POPs):state of the scienceJ. Environ Pollut, 1999, 100 (1/2/3): 209-221.2 Xu Diandou, Zhong Weike, Deng Linlin, et al. Regional distribution of organochlorinated pesticides in pine needles and its indication for socioeconomic developme

5、ntJ.Chemosphere, 2004, 54(6): 753- 752.3 农业部新疆农业发展专题研究课题组.新疆农业发展问题研究(上)J.中国农业资源与区划,2008,29(1): 1-6.Xinjiang Agricultural Development Special Research Task group of the Ministry of Agriculture. Studies on the issue of agriculture development in XinjiangJ. Chinese Journal of Agricultural Resources and

6、 Regional Planning,2008,29(1):1 -6. (in Chinese with English abstract)4 农业部新疆农业发展专题研究课题组.新疆农业发展问题研究(下)J.中国农业资源与区划,2008,29(2): 8- 12.Xinjiang Agricultural Development Special Research Task group of the Ministry of Agriculture. Studies on the issue of agriculture development in XinjiangJ. Chinese Jour

7、nal of Agricultural Resources and Regional Planning, 2008, 29(2):8- 12. (in Chinese with English abstract)5 Li Xinghong, Wang Wei, Wang Juan, et al. Contamination of soils with organochlorine pesticides in rban parks in Beijing,ChinaJ. Chemosphere, 2008, 70(9): 1660- 1668.6 Zhang Hong, Lu Yonglong,

8、Dawson R W, et al. Classification and ordination of DDT and HCH in soil samples from the Guanting Reservoir, ChinaJ. Chemosphere, 2005, 60(6):762- 769.7 Jiang Yufeng, Wang Xuetong, Jia Ying, et al. Occurrence,distribution and possible sources of organochlorine pesticides in agricultural soil of Shan

9、ghai, ChinaJ. Journal of Hazardous Materials, 2009, 170(2/3): 989-997.8 Gong Xiangyi, Qi Shihua, Wang Yanxin, et al. Historical contamination and sources of organochlorine pesticides in sediment cores from Quanzhou Bay, Southeast ChinaJ.万方数据 Marine Pollution Bulletin, 2007, 54(9): 1434-1440.9 Zhang

10、Zulin, Huang Jun, Yu Gang, et al. Occurrence of PAHs, PCBs and organochlorine pesticides in Tonghui River of Beijing, ChinaJ. Environ. Pollut, 2004, 130(2): 249-261.10 Li Xinghong, Zhu Youfeng, Liu Xiufen, et al. Distribution of HCHs and DDTs in Soils from Beijing City, ChinaJ.Archives of Environmen

11、tal Contamination and Toxicology,2006, 51(3): 329-336.11 Heberer T, Dnnbier U. DDT metabolite bis(chlorophenyl)acetic acid: the neglected environmental contaminantJ.Environ Sci Technol, 1999, 33(14): 2346-2351.12 Jaga K, Dharmani C. Global surveillance of DDT and DDE levels in human tissuesJ. Int J

12、Occup Med Environ Health.2003, 16(1): 7-20.13 Qiu X, Zhu T, Yao B, et al. Contribution of dicofol to the current DDT pollution in ChinaJ. Environ Sci Technol.2005, 39(12): 4385-4390.14 Schuphan I, Sajko B, Ballschmiter K Z. On chemical andphotochemical breakdown of the cyclodiene-insecticides,aldrin

13、, dieldrin, endosulfan and other hexachlorobicyclo-(2.2.1)-hept-derivativesJ. Z Naturforseh, 1972, 276: 147-156.15 Sovocool G W, Lewis R G, Harless R L, et al. Analysis of technical chlordane by gas chromatography-mass spectrometryJ.Anal Chem, 1997, 49(6): 734-740.16 Bidleman T F, Jantunen L M M, He

14、lm P A, et al. Chlordane enantiomers and temporal trends of chlordane isomers in Arctic airJ. Environ Sci Technol, 2000, 36(4): 539-544.17蒋煜峰,王学彤,孙阳昭,等.上海市城区土壤中有机氯农药残留研究J.环境科学,2010, 31(2): 409-414.Jiang Yufeng, Wang Xuetong, Sun Yangzhao, et al.Residues of organochlorine pesticides in urban soil of

15、ShanghaiJ.Environmental Science, 2010, 31(2): 409-414. (in Chinese with English abstract)18孙剑辉,王国良,张干,等.黄河表层沉积物中有机氯农药的相关性分析与风险评价J.环境科学学报,2008,28(2): 342-348.Sun Jianhui, Wang Guoliang, Zhang Gan, et al. Correlation analysis and risk assessment of organochlorine pesticides in surface sediments from t

16、he Yellow RiverJ. Acta Scientiae Circumstantiae, 2008, 28(2): 342-348. (in Chinese with English abstract)19李世华,牛铮,路鹏,等.基于主成分分析红壤有效含水量估算模型J.农业工程学报,2007, 2(5): 92-94.Li Shihua, Niu Zheng, Lu Peng, et al.Red soil available water capacity statistical model based on principal componet analysisJ. Transact

17、ions of the CSAE, 2007, 23(5): 92-94.(in Chinese with English abstract)20马瑾,邱兴华,周永章,等.湛江市土壤有机氯农药残留状况及空间分布特征J.地理学报,2001, 65(1): 103-112.Ma Jin, Qiu Xinghua, Zhou Yongzhang, et al. Residues and spatial distributions of OCPs in Soils of ZhanjiangJ. Acta Geographica Sinica, 2001, 65(1): 103-112. (in Chi

18、nese with English abstract)21胡大立.应用灰色系统理论评价企业竞争力J.科技进步与对策,2003,10(1): 159-161.Hu Dali. Applying the Gray Theory evaluating the competitive competence of enterprisesJ.Science & Technology Progress and Policy, 2003,10 (1): 159- 161.22崔嵩,田崇国,郭亮,等.基于灰色关联分析法的土壤中有机氯农药污染评价研究J.黑龙江大学自然科学学报,2011, 28(1): 96-10

19、0Cui Song, Tian Chongliang, Guo Liang, et al.Analysis of contaminated pollution of organo-chlorine pesticides in soils based on gray correlative analysis J. Journal of Natural Science of Heilongjiang University, 2011, 28(1):96- 100.Distribution and risk assessment of organochlorine pesticides (OCPs) in soils of typical agricultural regions in XinjiangRan DanLu JianjiangYao XiaoruiLiu ZilongDu ZhijianZhang Shuo万方数据

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