2022年安徽省六校教育研究会高三素质测试化学试题含答案 .pdf

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1、满分 100 分考试时间 100 分钟可能用到的相对原子质量H1 C12 N14 O16 Na23 Mg24 Al27 Si28 Cl35.5 Ca40 Mn55 Fe56 Cu64 一、选择题（本题共40 分，每小题 2 分，每小题只有一个正确选项）1在火星上工作的美国“勇气号”、“机遇号”探测车的一个重要任务就是收集有关 Fe2O3及硫酸盐的信息，以证明火星上存在或曾经存在过水。以下叙述正确的是()A铝热剂就是单指Fe2O3粉和铝粉的混合物B检验从火星上带回来的红色物质是否是Fe2O3的操作步骤为：样品 粉碎加水溶解 过滤向滤液中滴加 KSCN 溶液C还原 a mol Fe2O3所需 H2

2、、Al、CO 的物质的量之比为 323 D明矾属于硫酸盐，含结晶水，是混合物2过氧化钠与 CO2作用，反应的化学方程式为2Na2O22CO2=2Na2CO3O2。当 0.2 mol Na182O2与足量 CO2完全反应后，下表对生成物Na2CO3和 O2的描述中正确的是()Na2CO3的质量关于 O2的描述A 21.2 g O2的摩尔质量是 36 g mol1B 21.6 g 生成标准状况下 O2的体积为 2.24 L C 21.6 g O2的摩尔质量是 34 g mol1D 22.4 g 生成标准状况下 O2的体积为 2.24 mL 3下列实验与物质微粒大小无直接关系的是()4向一定量的Na

3、OH 溶液中逐滴加入AlCl3溶液，生成沉淀Al(OH)3的量随 AlCl3加入量的变化关系如图所示。则下列离子组在对应的溶液中一定能大量共存的是()Aa 点对应的溶液中：Na、Fe3、SO24、HCO3Bb 点对应的溶液中：Na、S2、SO24、ClCc 点对应的溶液中：Ag、Ca2、NO3、FDd 点对应的溶液中：K、NH4、I、CO235有编号为 A、B、C、D 的四瓶无色液体，仅知道是1%酚酞、0.1 mol L1NaOH 溶液、0.1 mol L1盐酸和 0.1 mol L1NaCl 溶液。化学老师现要求甲、乙、丙、丁四位学生对它们进行鉴别，规定每人只需鉴别两瓶溶液，如果两瓶溶液鉴别

4、都正确，得满分，如果只有一瓶鉴别正确，则算及格。以下是四位学生的鉴别结果：甲A 为 0.1 mol L1盐酸D 为 0.1 mol L1 NaCl 溶液老师评价：四位学生都及格，但是没有一个得满分乙A 为 0.1 mol L1 NaOH 溶液C 为 0.1 mol L1盐酸丙A 为 1%酚酞B 为 0.1 mol L1盐酸丁D 为 0.1 mol L1盐酸B 为 0.1 mol L1 NaOH 溶液下列结论正确的是()AA 为 1%酚酞BB 为 0.1 mol L1 NaCl 溶液CC 为 0.1 mol L1 NaOH 溶液DD 为 0.1 mol L1盐酸6对含微量 I的某样品进行 I化学

5、定量测定，有以下两种途径，最后均是以淀粉作指示剂，用 Na2S2O3标准溶液滴定以求得I的浓度。下列分析正确的是()已知：5IIO36H=3H2O3I2I3Br2(过量)3H2O=6H6BrIO3方法一I(样品)过量 Br2IO3煮沸除 Br2盐酸酸化 KI调节 pH7I2 Na2S2O3I方法二I(样品)适量 Br2I2 Na2S2O3IA方法二对样品所做处理操作简便，用作微量I的测定更准确B当待测液由无色变为蓝色时即达到滴定终点C方法一与方法二测量出的样品浓度比为61 D假设各步骤操作均得当，方法一所消耗Na2S2O3标准溶液的体积是方法二的 6 倍7杨老师在课堂上出示两瓶失去标签的Na2

6、CO3和 NaHCO3无色饱和溶液，希望班里同学提出简便的鉴别方法，该班同学踊跃提出看法，其中不合理的是()用干燥的 pH 试纸检验，pH 大的是 Na2CO3取同量的溶液于两支试管中，各滴入酚酞试液，红色较深的是Na2CO3取同量的溶液于两支试管中，加热，有气泡产生的是NaHCO3取同量的溶液于两支试管中，逐滴加入稀盐酸，开始就有气体放出的是文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文

7、档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY

8、9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D

9、6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT

10、5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U

11、9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 Z

12、E2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6

13、E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6文档编码:CY9T4E2D6Z4 HT5C5F1U9U10 ZE2M9Y6E10F6NaHCO3取同量的溶液于两支试管中，滴加 BaCl2溶液，生成白色沉淀的是Na2CO3取同量的溶液于两支试管中，滴加Ba(OH)2溶液，生成白色沉淀的是Na2CO3ABCD8下图中 a、b、c 表示相应仪器中加入的试剂，可用下图装置制取、净化、收集的气体是()编号气体a b c A NH3浓氨水生石灰碱石灰B CO2盐酸碳酸钙饱和 NaHCO3C NO 稀硝酸铜屑H2O D NO2浓硝酸铜屑NaOH 溶液9等物质的量

14、的 N2、O2、CO2混合气体通过 Na2O2后，体积变为原体积的89(同温同压)，这时混合气体中N2、O2、CO2的物质的量之比为()A341 B332 C673 D690 10对溶液中的反应，如图图像中 m表示生成沉淀的物质的量，n 表示参加反应的某一种反应物的物质的量，则下列叙述中错误的是()A符合甲图像的两种反应物可以是AlCl3和 NaOH B符合乙图像的两种反应物可以是Ca(OH)2和 CO2C符合丙图像的反应可以是在Ca(OH)2和 KOH 的混合溶液中通入CO2D符合丙图像的反应可以是在NH4Al(SO4)2溶液中加入 NaOH 11向含有 Fe2、I、Br的溶液中通入适量氯气

15、，溶液中各种离子的物质的量变化如下图所示。有关说法不正确的是()A线段 BC 代表 Fe3物质的量的变化情况B原混合溶液中 c(FeBr2)6 mol/L C 当通入 Cl2 2 mol 时，溶液中已发生的离子反应可表示为：2Fe22I2Cl2=2Fe3I24ClD原溶液中 n(Fe2)n(I)n(Br)213 文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9

16、HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O

17、8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6

18、ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U1

19、0A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I

20、2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:

21、CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B

22、3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I212半导体工业用石英砂做原料通过三个重要反应生产单质硅SiO2(s)2C(s)=Si(s)2CO(g)H1+682.44 kJ mol1(石英砂)(粗硅)Si(s)2Cl2(g)=SiCl4(l)H2657.01 kJ mol1(粗硅)SiCl4(l)2Mg(s)=2MgCl2(s)Si(s)H3625.63 kJ mol1(纯硅)若生产 1.00 kg纯硅放出的热量为()A21.44 kJ B600.20 kJ C21435.71 kJ D1965

23、.10 kJ 13可逆反应 aA(g)bB(g)cC(g)dD(s)；HQ kJ/mol，反应过程中，当其他条件不变时，某物质在混合物中的含量与温度(T)、反应速率(v)与压强的关系如图所示。据图分析，以下说法正确的是()AT10 B增大压强，B 的转化率减小C当反应达平衡时，混合气体的密度不再变化Dabcd14已知反应 2CH3OH(g)CH3OCH3(g)H2O(g)某温度下的平衡常数为400。此温度下，在体积恒定的密闭容器中加入一定量的CH3OH，反应到某时刻测得各组分的浓度如下：物质CH3OH CH3OCH3H2O 浓度/mol L10.44 0.6 0.6 下列叙述中正确的是()A该

24、反应的平衡常数表达式为Kc(CH3OCH3)c(H2O)/c(CH3OH)B此时正、逆反应速率的大小：v正v逆C若经 10 min 后反应达到平衡，此时c(CH3OH)0.04 mol/L D010min 内平均反应速率 v(CH3OH)1.6 mol/(Lmin)15已知 25时，Ka(HF)3.6 104，Ksp(CaF2)1.46 1010。现向 1 L 0.2 mol L1HF 溶液中加入 1 L 0.2 mol L1CaCl2溶液，则下列说法中，正确的是()A25时，0.1 mol L1HF 溶液中 pH1 BKsp(CaF2)随温度和浓度的变化而变化C该体系中没有沉淀产生D该体系中

25、 HF 与 CaCl2反应产生沉淀文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL

26、10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A

27、1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文

28、档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM

29、3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M

30、8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA

31、4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I216查处酒后驾驶采用的“便携式乙醇测量仪”以燃料电池为工作原理，在酸性环境中，理论上乙醇可以被完全氧化为CO2，但实际乙醇被氧化为X，

32、其中一个电极的反应式为CH3CH2OH2e=X2H。下列说法中正确的是()A电池内部 H由正极向负极移动B另一极的电极反应式为O24e2H2O=4OHC乙醇在正极发生反应，电子经过外电路流向负极D电池总反应式为2CH3CH2OHO2=2CH3CHO2H2O 17 某储能电池的原理如图所示，溶液中 c(H)2.0 mol L1，阴离子为 SO24，a、b 均为惰性电极，充电过程中左槽溶液颜色由蓝色变为黄色。下列叙述正确的是()A当右槽溶液颜色由绿色变为紫色时，电池中能量转化形式为化学能转化为电能B充电过程中，a 极的反应式为VO2 eH2O=VO22HC储能电池 a、b 两极间的电解质溶液中通过

33、电子的定向移动形成闭合回路D放电时，当转移的电子数为6.02 1023时，从右槽迁移进入左槽的H的物质的量为 2 mol 18具有显著抗癌活性的10羟基喜树碱的结构如图所示。下列关于 10羟基喜树碱的说法正确的是()A分子式为 C20H16N2O5B不能与 FeCl3溶液发生显色反应C不能发生酯化反应D一定条件下，1 mol 该物质最多可与 1 mol NaOH 反应19向 mg 镁和铝的混合物中加入适量的稀硫酸，恰好完全反应生成标准状况下的气体 bL。向反应后的溶液中加入cmol/L 氢氧化钾溶液 VmL，使金属离子刚好沉淀完全，得到的沉淀质量为ng。再将得到的沉淀灼烧至质量不再改变为止，得

34、到固体 pg。则下列关系不正确的是()Ac1000b11.2VBpmVc125Cnm17VcD.53mp179m20一定量的 CuS和 Cu2S的混合物投入足量的HNO3中，收集到气体 VL（标准状况），向反应后的溶液中（存在Cu2+和 SO42-）加入足量 NaOH，产生蓝色沉淀，过滤，洗涤，灼烧，得到CuO12.0g，若上述气体为 NO和 NO2的混合物，且体积比为 11，则 V 可能为文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA

35、4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O

36、7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL

37、10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A

38、1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文

39、档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM

40、3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M

41、8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2A9.0L B13.5L C15.7L D16.8L 二、非选择题（本题包括4 小题，共 60分）21(12 分)X、Y、Z、Q、W、R 六种短周期元素原子序数依次增大。化合物甲由 X、Z、Q 三种元素组成，常温下0.1 mol/L 甲溶液的 pH13。工业上常用电解饱和 QR 溶液生成甲；化合物乙由 X、R 两种元素组成；请回答以下问题：(1)Q 的原子结构示意图为 _

42、。(2)Y 元素的单质能发生如图所示的转化，则Y 元素为_(用元素符号表示)。在甲溶液中通入足量YZ2气体，所得溶液呈碱性，原因是_(用离子方程式和必要的文字说明)。(3)W 的单质既能与甲溶液反应，又能与乙溶液反应。常温下，将W 的单质和甲溶液混合，发生反应的离子方程式为：_。Q、W 两种元素金属性的强弱为Q_W(填“”)；下列表述中证明这一事实的是 _。aQ 的单质的熔点比W 单质低b Q 的最高价氧化物的水化物的碱性比W 的最高价氧化物的水化物的碱性强cW 的原子序数大22(17 分)化合物 M 是一种治疗心脏病药物的中间体，以A 为原料的工业合成路线如下图所示。文档编码:CM3E2B3

43、M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 H

44、A4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8

45、O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 Z

46、L10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10

47、A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2

48、文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:C

49、M3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2文档编码:CM3E2B3M8I9 HA4T5O8O7U6 ZL10U10A1I7I2已知：RONaR ClROR NaCl 根据题意完成下列填空：(1)写出反应类型。反应_ 反应 _(2)写出结构简式。A_ _C_ _。(4)由 C 生成 D 的另一个反应物是 _，反应条件是

50、 _。(5)写出由 D 生成 M 的化学反应方程式。_、_ _。23(15 分)废易拉罐的成分比较复杂，据查，铝易拉罐各部分成分及含量(质量百分含量)见表：Si Fe Cu Mn Mg Cr Zn Ti Al 罐身/%0.3 0.7 0.25 0.25 1.01.5 其余罐盖/%0.2 0.35 0.15 0.20.5 4.05.0 0.1 0.25 其余拉环/%0.2 0.35 0.15 0.20.5 3.04.0 0.1 0.25 0.1 其余为了验证罐身的组成成分，进行了如下实验：【实验仪器与药品】仪器：酒精灯、烧杯、试管、试管夹、漏斗、滤纸、铁圈、玻璃棒、砂纸、文档编码:CM3E2B3