Urea 尿素 MSDS 英文(6页).doc

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1、-Urea 尿素 MSDS 英文-第 6 页Material Safety Data SheetUrea MSDSSection 1: Chemical Product and Company IdentificationProduct Name: UreaCAS#: 57-13-6RTECS: YR6250000TSCA: TSCA 8(b) inventory: UreaSynonym: CarbamideChemical Name: carbonyldiamideChemical Formula: (NH2)2CO or CH4N2OSection 2: Composition and

2、Information on Ingredients Composition:NameCAS #% by WeightUrea57-13-6100Toxicological Data on Ingredients: Urea: ORAL (LD50): Acute: 8471 mg/kg Rat. 11000 mg/kg Mouse.Section 3: Hazards IdentificationPotential Acute Health Effects: Hazardous in case of skin contact (irritant), of eye contact (irrit

3、ant), of ingestion, of inhalation.Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available.MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells.TERATOGENIC EFFECTS: Not available.DEVELOPMENTAL TOXICITY: Not available.The substance may be toxic to blood, cardiovascular system.Repeated

4、 or prolonged exposure to the substance can produce target organs damage.Section 4: First Aid MeasuresEye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for atleast 15 minutes. Cold water may be used. Get medical attention.Skin Contac

5、t:In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Removecontaminated clothing and shoes. Cold water may be used. Wash clothing before reuse. Thoroughly clean shoesbefore reuse. Get medical attention.Serious Skin Contact:Wash with a disinfe

6、ctant soap and cover the contaminated skin with an anti-bacterial cream. Seek medicalattention.Inhalation:If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Getmedical attention.Serious Inhalation: Not available.Ingestion: Do NOT i

7、nduce vomiting unless directed to do so by medical personnel. Never give anything by mouth to anunconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention ifsymptoms appear.Serious Ingestion: Not available.Section 5: Fire and Explosion DataFlammability

8、of the Product: May be combustible at high temperature.Auto-Ignition Temperature: Not available.Flash Points: Not available.Flammable Limits: Not available.Products of Combustion: These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2.).Fire Hazards in Presence of Various Substances: S

9、lightly flammable to flammable in presence of heat.Explosion Hazards in Presence of Various Substances: Risks of explosion of the product in presence of mechanical impact: Not available.Risks of explosion of the product in presence of static discharge: Not available.Fire Fighting Media and Instructi

10、ons:SMALL FIRE: Use DRY chemical powder.LARGE FIRE: Use water spray, fog or foam. Do not use water jet.Special Remarks on Fire Hazards: Not available.Special Remarks on Explosion Hazards: Not available.Section 6: Accidental Release MeasuresSmall Spill: Use appropriate tools to put the spilled solid

11、in a convenient waste disposal container. Finish cleaning byspreading water on the contaminated surface and dispose of according to local and regional authorityrequirements.Large Spill: Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on

12、 the contaminated surface and allow to evacuate through the sanitary system.Section 7: Handling and StoragePrecautions:Keep locked up. Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk,evaporate the residue under a fume hood. Ground all equipment containing m

13、aterial. Do not ingest. Do notbreathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratoryequipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact withskin and eyes. Keep away from incompatibles such

14、 as oxidizing agents.Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 23C (73.4F).Section 8: Exposure Controls/Personal ProtectionEngineering Controls:Use process enclosures, local exhaust ventilation, or other engineering controls to keep ai

15、rborne levels belowrecommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure toairborne contaminants below the exposure limit.Personal Protection: Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equival

16、ent.Gloves.Personal Protection in Case of a Large Spill: Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this

17、 product.Exposure Limits: Not available.Section 9: Physical and Chemical PropertiesPhysical state and appearance: Solid. (Crystals solid.)Odor: Almost odorless; May gradually develop slight odor of ammonia, especially in presence of moisture.Taste: Cooling. SalineMolecular Weight: 60.06 g/moleColor:

18、 White.pH (1% soln/water): Not available.Boiling Point: Not available.Melting Point: 132.7C (270.9F)Critical Temperature: Not available.Specific Gravity: 1.323 (Water = 1)Vapor Pressure: Not applicable.Vapor Density: 2.07 (Air = 1)Volatility: Not available.Odor Threshold: Not available.Water/Oil Dis

19、t. Coeff.: Ionicity (in Water): Not available.Dispersion Properties: See solubility in water.Solubility: Easily soluble in cold water, hot water.Section 10: Stability and Reactivity DataStability: The product is stable.Instability Temperature: Not available.Conditions of Instability: Excess heat, ex

20、cess dust generation, incompatible materials.Incompatibility with various substances: Reactive with oxidizing agents.Corrosivity: Not available.Special Remarks on Reactivity:Hygroscopic. Aborbs moisture from air.Reacts violently with Gallum Perchlorate. Reacts with chlorine to form chloramines.It al

21、so reacts with the following: sodium hypochlorite, sodium nitrate, calcium hypochlorite, NaNO2, P2Cl5,nitrosyl perchlorate, strong oxidizing agents (permanganate, nitrate, dichromate, chloride)Special Remarks on Corrosivity: Not available.Polymerization: Will not occur.Section 11: Toxicological Info

22、rmationRoutes of Entry: Inhalation. Ingestion.Toxicity to Animals: Acute oral toxicity (LD50): 8471 mg/kg Rat.Chronic Effects on Humans:MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells.May cause damage to the following organs: blood, cardiovascular system.Other Toxic Effects on Humans: Hazar

23、dous in case of skin contact (irritant), of ingestion, of inhalation.Special Remarks on Toxicity to Animals: Not available.Special Remarks on Chronic Effects on Humans:May cause adverse reproductive effects (fetotoxicity) and genetic material (mutagenicity) based on animal studies.Passes through the

24、 placental barrier in human and is present in breast milk.Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects:Skin: Causes skin irritation.Eyes: Causes eye irritation.Inhalation: Causes irritation of the respiratory tract, nose, and throat, coughing and sneezing. May also

25、 affectblood, metabolsim and urinary system.Ingestion: Causes digestive (gastrointestinal) tract irritation with nausea, vomiting, and diarrhea. May affectbehavior (altered sleep time, change in motor activity), cardiovascular system (heart rate), and the brain. Mayalso affect the blood and may caus

26、e tumorigenic effects.Chronic Potential Health Effects: Prolonged exposure may cause adverse reproductive effects. Laboratoryexperiments on animals have resulted in mutagenic effects. Prolonged exposure or exposure at highconcentrations may cause eye damage.Section 12: Ecological InformationEcotoxic

27、ity: Not available.BOD5 and COD: Not available.Products of Biodegradation:Possibly hazardous short term degradation products are not likely. However, long term degradation products mayarise.Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.S

28、pecial Remarks on the Products of Biodegradation: Not available.Section 13: Disposal ConsiderationsWaste Disposal:Waste must be disposed of in accordance with federal, state and local environmentalcontrol regulations.Section 14: Transport InformationDOT Classification: Not a DOT controlled material

29、(United States).Identification: Not applicable.Special Provisions for Transport: Not applicable.Section 15: Other Regulatory InformationFederal and State Regulations:Minnesota: UreaTSCA 8(b) inventory: UreaOther Regulations:OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.

30、1200).EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.Other Classifications:WHMIS (Canada): Not controlled under WHMIS (Canada).DSCL (EEC):R36/38- Irritating to eyes and skin.R40- Possible risks of irreversibleeffects.S24/25- Avoid contact with skin and e

31、yes.HMIS (U.S.A.):Health Hazard: 2Fire Hazard: 1Reactivity: 0Personal Protection: ENational Fire Protection Association (U.S.A.):Health: 2Flammability: 1Reactivity: 0Specific hazard:Protective Equipment:Gloves.Lab coat.Dust respirator. Be sure to use anapproved/certified respirator orequivalent.Splash goggles.