聚醚密封胶ppt课件.ppt

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1、“雪亮工程是以区（县）、乡（镇）、村（社区）三级综治中心为指挥平台、以综治信息化为支撑、以网格化管理为基础、以公共安全视频监控联网应用为重点的“群众性治安防控工程”。“雪亮工程是以区（县）、乡（镇）、村（社区）三级综治中心为指挥平台、以综治信息化为支撑、以网格化管理为基础、以公共安全视频监控联网应用为重点的“群众性治安防控工程”。History of MS Polymer and SILYL78MS Takasago Plantwas in operation82MS sealant tookroot in Market 85 89Penetration to adhesive market.

2、SILYL was launched. 96Expand into over sea market.KBLabo was in operation.97KB plant was in operation.U.S.A. Lab. was established.EPION plant was operated in Kashima.Grade ChangePolymer Design for Construction Sealant(2-Part)Durability(JIS9030)(Hardening Catalyst Formulation Technology)Improvement o

3、f Curability9485Residual Tack/Dirt PickingPrefab House, Siding BoardMarketLow Modulus, Durability, PaintabilityNon Staining / Exellent durability80Higher Weatherability(Glazing in Europe) Dehydration, Fast Cure,Primerless Adhesion1-Part Formulation TechnologyLower Mod.Higher ElongationHigher Recover

4、y(NonStaining Sealant)Ideal ConstructionSealant1-Part Technology(Epoxy/Ketimine)82Expansion to Adhesives MarketAcrylic ModifyTechnology(MA)Universal AdhesionEarly Grab Property(Alternative for Contact Cement)Non-Solvent Adhesives forGeneral Industry & ConstructionApplication for AutomotiveA variety

5、ofSpecific ApplicationsSprayable SealantD.G.Sealant(After market)Application Spread1-Part Elastic Adhesives87General Industrial SealantEpoxy BlendTechnology(SILYL)High Strength High HardnessWater-resistance 2-Part ElasticAdhesives Construction & Civil-engineering MarketTile Bonding, Stone- Back Trea

6、tment, Aluminum-Honeycomb, Panel BondingExpansion of New Application Construction Civil-engineering Industrial UseAutomotiveElectronic etc. Sealant Adhesives PSA Coating etc.IDG SealantNew OligomersResearch90In-line and Molding MarketCrosslinker / CatalystPolyisobutylene BackboneExcellent Weatherabi

7、lity, Heat Resistance, Gas Permeability, Electrical Properties New Curing System (Addition Reaction)Fast Cure at High TemperatureAcrylic backbone“雪亮工程是以区（县）、乡（镇）、村（社区）三级综治中心为指挥平台、以综治信息化为支撑、以网格化管理为基础、以公共安全视频监控联网应用为重点的“群众性治安防控工程”。01000020000300004000050000600001977198219871992199720022007USAEuropeJapa

8、nUSAEuropeJapan(MT)Year01000020000300004000050000600001977198219871992199720022007USAEuropeJapanUSAEuropeJapan(MT)Year“雪亮工程是以区（县）、乡（镇）、村（社区）三级综治中心为指挥平台、以综治信息化为支撑、以网格化管理为基础、以公共安全视频监控联网应用为重点的“群众性治安防控工程”。OCHCH2OCH3Si(OCH3)2CH3(CH3O)2SiCH3nGood chemical stabilitywithout catalyst* Low viscosity* Good com

9、patibility with various additives (SP value = 8 9)A Wide Variety of Formulationsand Easy Production of SealantsConstruction, General Industry, Automotive etc.A Wide Variety of ApplicationsChemical Structure & Characteristics“雪亮工程是以区（县）、乡（镇）、村（社区）三级综治中心为指挥平台、以综治信息化为支撑、以网格化管理为基础、以公共安全视频监控联网应用为重点的“群众性治

10、安防控工程”。X(CH3O)2SiCH3Si-OHCH3HO-SiCH3Si O SiCH3OCH3OSiCH3SiCH3Catalyst+H2OSi(OCH3)2CH3nOMS Polymer and Curing MechanismXMS =EPION =OCH3CH3CH3PolymerFormulationMarket & Application- Good workability- Water resistance- Higher hardness- Higher strength - Excellent weatherabilityheat-resistanceweatherabi

11、lity CatalystAdhesion promoterDehydratorStabilizerThixotropic agentFillerPlasticizer Fungicide- Sealant for high-rise building- Sealant for prefab.house- Fire resistant sealant- Adhesives for panel bonding- Adhesives for parquet- Multipurpose sealant/ adhesives- Alternative for solvent-based adhesiv

12、e - DG sealant- Adhesives for container- Adhesives for honeycomb- Adhesives for tile bonding- Floor joint sealant- Coating on concrete- F(c)IPG,PSA,Potting,Foam, Molding,Modifier etc. for the Specified applicationMS(Polyether)Polymer BlendAcrylic (MA)Epoxy (SILYL)- Higher weatherbility- Better adhes

13、ion- Early grabEPION(Polyisobutylene)heat-resistancegas-permeabilityelectrical properties? (Polyacrylic)-Excellent oil-resistancestorage-stabilityweatherabilityadhesion, durabilitypaintabilitynon-stainingConstructionDIYIndustry/AutomotiveCivil-engineeringNew markets“雪亮工程是以区（县）、乡（镇）、村（社区）三级综治中心为指挥平台、

14、以综治信息化为支撑、以网格化管理为基础、以公共安全视频监控联网应用为重点的“群众性治安防控工程”。What is so good about MS Sealant?Durability MS sealant has superior durability, excellent weather resistance and high elasticity.Adhesion MS Sealant shows good adhesion without primer on various substrate.Paintability MS sealant can be painted with va

15、rious kinds of paints.Non-stone staining MS sealant has excellent non-staining characteristics against stones, tiles, plates.Quick cure MS sealant cures quickly even at low temperatures.Easy handling Viscosity of MS sealant is stable over a wide range of temperature. Its extrudability is excellent e

16、ven at cold sites.Odorless MS sealant has no unpleasant odour such as mercaptan and acetic acid odor.Non-isocyanate: MS sealant is low toxic when at work, because MS sealant is not including any isocyanate.“雪亮工程是以区（县）、乡（镇）、村（社区）三级综治中心为指挥平台、以综治信息化为支撑、以网格化管理为基础、以公共安全视频监控联网应用为重点的“群众性治安防控工程”。Outdoor Exp

17、osure“雪亮工程是以区（县）、乡（镇）、村（社区）三级综治中心为指挥平台、以综治信息化为支撑、以网格化管理为基础、以公共安全视频监控联网应用为重点的“群众性治安防控工程”。Adhesion on Various Substrates“雪亮工程是以区（县）、乡（镇）、村（社区）三级综治中心为指挥平台、以综治信息化为支撑、以网格化管理为基础、以公共安全视频监控联网应用为重点的“群众性治安防控工程”。M SS RPSPUW ater baseA cryl i c Pai nt(L)W ater baseA cryl i c Pai nt(M )W ater baseA cryl i c Pai

18、nt(N )Paintability with Water Based Paint“雪亮工程是以区（县）、乡（镇）、村（社区）三级综治中心为指挥平台、以综治信息化为支撑、以网格化管理为基础、以公共安全视频监控联网应用为重点的“群众性治安防控工程”。Migration StainingDirt StreakingHydrophobic StainingMSConstruction formulationNon-staining SRNormal SRMSNon-staining formulationLessNonNonNGNonNon?NGNGNGNonNonTypes of Stone St

19、aining“雪亮工程是以区（县）、乡（镇）、村（社区）三级综治中心为指挥平台、以综治信息化为支撑、以网格化管理为基础、以公共安全视频监控联网应用为重点的“群众性治安防控工程”。MSSRSR*PSPUGranite (Out door exposure for 6 years)PSMSSRSR*Artificial Marble (Out door exposure for 4 years)Remarks;SR* : One Part TypeOthers : Two part TypeOutdoor Staining Test “雪亮工程是以区（县）、乡（镇）、村（社区）三级综治中心为指挥平

20、台、以综治信息化为支撑、以网格化管理为基础、以公共安全视频监控联网应用为重点的“群众性治安防控工程”。Curability at Low Temperature“雪亮工程是以区（县）、乡（镇）、村（社区）三级综治中心为指挥平台、以综治信息化为支撑、以网格化管理为基础、以公共安全视频监控联网应用为重点的“群众性治安防控工程”。Gunnability at Wide Range Temp.“雪亮工程是以区（县）、乡（镇）、村（社区）三级综治中心为指挥平台、以综治信息化为支撑、以网格化管理为基础、以公共安全视频监控联网应用为重点的“群众性治安防控工程”。Anti-Fungus2phr of fung

21、icide (Metatine 55-20)MSPUSRAccording to ISO-846 Method BS am pl e nam eM etati n5 5 -2 0R esul t(seal ant)phrI S O -8 4 6 - m oul dsM S02M S20P U-3S R-5MS sealant/ adhesives“雪亮工程是以区（县）、乡（镇）、村（社区）三级综治中心为指挥平台、以综治信息化为支撑、以网格化管理为基础、以公共安全视频监控联网应用为重点的“群众性治安防控工程”。Properties of MS PolymerPolymer GradeTypeVi

22、scosity (Pa.s)ApplicationS203HLow Mod.8Construction and S303HMid Mod.12Industrial AdhesiveSAX350High Mod. Low viscosity6Industrial AdhesiveSAX400High Strength24EST280High Mod. Low viscosity8WoodFloor AdhesiveSAT010Reactive Diluent0.7MAX923High weatherability30Construction and MAX951Good Alkid painta

23、bility50Industrial Adhesive“雪亮工程是以区（县）、乡（镇）、村（社区）三级综治中心为指挥平台、以综治信息化为支撑、以网格化管理为基础、以公共安全视频监控联网应用为重点的“群众性治安防控工程”。Application for Polymer Grade“雪亮工程是以区（县）、乡（镇）、村（社区）三级综治中心为指挥平台、以综治信息化为支撑、以网格化管理为基础、以公共安全视频监控联网应用为重点的“群众性治安防控工程”。(H3CO)2SiOCH-CH2OCH3nSi(OCH3)2CH3CH3MS Polymer 100 phrFiller CaCO3, TiO2 talc,

24、 clayPlasticizer phthalate PPG,.Pigment TiO2 carbon blackThixotrope polyamidwax castor oilStabilizer anti-oxidant UV absorber light stabilizerDehydrator alkoxysilaneAdhesion promoter silane coupling agentCatalyst Tin-compound 100-300 phr10-80 phr0-6 phr0.5-2 phr1-5 phr1-6 phr1-6phrMS Typical Formula

25、tion“雪亮工程是以区（县）、乡（镇）、村（社区）三级综治中心为指挥平台、以综治信息化为支撑、以网格化管理为基础、以公共安全视频监控联网应用为重点的“群众性治安防控工程”。Low & Middle Mod. For Construction & DIYFormulationFormulation NoKB-252Polymer content (%)24.3MS polymerS203H60S303H40PlasticizerDIUP70FillerC110S200TiO2Bayer RFK-210Thixotropic agentCrayvallac Super20UV-stabilize

26、rT-3271Light stabilizerT-7701Moduluslowering agentSMG, Dehydat 83123Dehydrating agentVTMO3Adhesion promotorDAMO2Hardening catalystU220H1TOTAL411Properties (KB-252)Tensile strengthM100MPa0.35by dumbbell shapeTB1.027d(23C)EB%820HardnessShore A-23Viscosityat 0.1s-14240by rheometerat 5 s-1Pas280at 10 s-

27、1160Tack free timehh:mm1 : 20Adhesion in peel by hand7d(23C)ISO11600 25LM0.3877%M100(MPa)Rec.CFGlassUPCPVCAnodized Aluminum“雪亮工程是以区（县）、乡（镇）、村（社区）三级综治中心为指挥平台、以综治信息化为支撑、以网格化管理为基础、以公共安全视频监控联网应用为重点的“群众性治安防控工程”。Medium Mod DIYFormulationFormulation No.DKB-5Polymer content32.9wt%phrMS PolymerS303H100Plasti

28、cizerDIUP50CaCO3Winnofil SPM120TiO2RFK-220Thixotropic agentCrayvallac Super5HALSTinuvin 7701UV-stabilizerTinuvin 3271Dehydrate agentVTMO2Adhesion PromoterDAMO3CatalystU-2201.5Total303.5Properties (DKB-5)Viscosityat 0.1s-14990by rheometerat 5 s-1Pas218at 10 s-1138Tack free timemin14Curability in dept

29、hafter 1day3.2after 3days mm5.5after 7days9.5HardnessShore A-39Tensile strengthM500.58by dumbbell shapeM100MPa 0.9023Cx7daysTB2.38EB%496Adhesion in peel by hand GlassCFnon-primerUPCCF23Cx7daysPVCAFAnodizedAluminumCF“雪亮工程是以区（县）、乡（镇）、村（社区）三级综治中心为指挥平台、以综治信息化为支撑、以网格化管理为基础、以公共安全视频监控联网应用为重点的“群众性治安防控工程”。MS

30、/SILYL Modification TechnologyEPOXYSi-AcrylicMA2-Part1-PartSILYL/EPOXY(Ketimine System)SAX350SAX400MAX923MAX951MAX602Adhesive - Water- resistance - High Shore A (Hardness) - High StrengthSILYLSealant - Weatherability - Alkyd-paintabilityAdhesives - Universal Adhesion - Early Grab* Civil Engineering*

31、 Construction* Glazing* Marine* Transparent* DIY* General Industry* Transparent“雪亮工程是以区（县）、乡（镇）、村（社区）三级综治中心为指挥平台、以综治信息化为支撑、以网格化管理为基础、以公共安全视频监控联网应用为重点的“群众性治安防控工程”。MSEpoxy resinHardening cat. for STPEHardener for Epoxy Compatibilizer(aminosilane)Etc.uNon solventuLow viscosity (Transparent)uTough elast

32、omeruPhase separation (Opaque)DomainCured Epoxy particle( 0.05 0.5 m)TEMMatrixCured MS uSTPE can be reinforced with Epoxy resinMicro phase separation during cure at R.T.“雪亮工程是以区（县）、乡（镇）、村（社区）三级综治中心为指挥平台、以综治信息化为支撑、以网格化管理为基础、以公共安全视频监控联网应用为重点的“群众性治安防控工程”。0246810120 01010252540405050606075751001000 0202

33、0404060608080100100120120Lap shear strength (MPa)T - peel strength (N/25mm)Quantity of epoxy resin blended to 100phr of MS (phr)MS / BPA-DGE / TDMAMP / Organic-tin cat. / Aminosilane= 100 / X / 5 / 2 / 1 (phr)；Cohesion Failure；Adhesive Failure Adherend : AlCFMixture of CF and AFAF“雪亮工程是以区（县）、乡（镇）、村（

34、社区）三级综治中心为指挥平台、以综治信息化为支撑、以网格化管理为基础、以公共安全视频监控联网应用为重点的“群众性治安防控工程”。u Solubility Control : Selection of Particular Monomer ( R2 )u Application for High Weatherability Sealant Low Tg Acrylic Polymer (Selection of R1, R2) u Application for Multipurpose Adhesive High Tg Acrylic Polymer (Selection of R1, R2

35、)CHCH2OSi(OCH3)2O(CH3O)2SiCH3CH3CH3nCH2-CCH2-CR1R3Si(OCH3)x(CH3)3-xR1COOR2STPEAcrylic PolymerTransparent elastomer Micro phase separationTEMCompatible (Transparent)“雪亮工程是以区（县）、乡（镇）、村（社区）三级综治中心为指挥平台、以综治信息化为支撑、以网格化管理为基础、以公共安全视频监控联网应用为重点的“群众性治安防控工程”。Time(hr) until surface cracking on SWOM (Sealant thic

36、kness : 3mm)n Surface weatherability can be improved by acryl modified STPEn Clear sealant can be designed by acryl modified STPE0 010001000200020003000300040004000500050006000600070007000Acryl Modified STPESTPE0 010001000200020003000300040004000500050006000600070007000Acryl Modified STPESTPE“雪亮工程是以

37、区（县）、乡（镇）、村（社区）三级综治中心为指挥平台、以综治信息化为支撑、以网格化管理为基础、以公共安全视频监控联网应用为重点的“群众性治安防控工程”。n Multipurpose adhesives can be designed with acryl-modified MS ；Cohesion Failure；Adhesive Failure 02468ABSPCFRPMelaminePVCLap Shear Strength (MPa)STPESTPEAcryl-Modified STPEAcryl-Modified STPECF70AF30CFAFAFCF10AF90CF90AF10C

38、FCF40AF60CFCFAFCFAFAFCFCFCFCF40AF60CFCF10AF90“雪亮工程是以区（县）、乡（镇）、村（社区）三级综治中心为指挥平台、以综治信息化为支撑、以网格化管理为基础、以公共安全视频监控联网应用为重点的“群众性治安防控工程”。012345678910AdhesionQuick cureMechanical stability(cure/tempreture)Mechanical PropertiesLow temperaturegunnabilitySlump resistanceUV stabilityNon-dirt pick-upLess stone sta

39、iningPaintabilityEnvironmental FriendlinessStorage stabilityNon-bubblingS RP UM SDIYIndustrialConstructionConclusion“雪亮工程是以区（县）、乡（镇）、村（社区）三级综治中心为指挥平台、以综治信息化为支撑、以网格化管理为基础、以公共安全视频监控联网应用为重点的“群众性治安防控工程”。TypePolymer BackboneFunctional GroupSilicones Polyurethanes MSDimethoxymethylsilylPolypropyleneoxideX

40、 = - OCH3 , - O C CH3 or - O N = CCH3C2H5 OR - NCO( CH CH2 O )- C NHRNH C O CH3m= O On -Si O Si O Si -CH3CH3CH3CH3CH3CH3- Si X3nCH3CHCH2O(H3CO)2Si-RCH3 SiPU(H3CO)3Si-R( CH CH2 O )- C NHRNH C O CH3m= O OnTrimethoxysilylOther Technologies“雪亮工程是以区（县）、乡（镇）、村（社区）三级综治中心为指挥平台、以综治信息化为支撑、以网格化管理为基础、以公共安全视频监控联

41、网应用为重点的“群众性治安防控工程”。MS is very stable even with water if no catalyst is involved. The good non bubbling performance of MS sealants stems from this polymer stability.Polymer Stability 1“雪亮工程是以区（县）、乡（镇）、村（社区）三级综治中心为指挥平台、以综治信息化为支撑、以网格化管理为基础、以公共安全视频监控联网应用为重点的“群众性治安防控工程”。Viscosity stability leads to:- les

42、s storage problem- long shelf time- reproduct with same property Polymer Stability 2“雪亮工程是以区（县）、乡（镇）、村（社区）三级综治中心为指挥平台、以综治信息化为支撑、以网格化管理为基础、以公共安全视频监控联网应用为重点的“群众性治安防控工程”。The formulation with SAX260 showed fast strength build up.Strength Build-Up“雪亮工程是以区（县）、乡（镇）、村（社区）三级综治中心为指挥平台、以综治信息化为支撑、以网格化管理为基础、以公共安

43、全视频监控联网应用为重点的“群众性治安防控工程”。MS PolymerSilyl modified polyurethaneCurrentTMS/DMSOr TMSConventional methodIsocyanatesilane methodWacker alpha silanePolymer / Sealant production process SupplierKANEKAKANEKABAYER, HANSE, Momentive,Self production (SIKA, KONISHI etc)BAYER, WACKER,Self production(HENKEL etc)

44、WACKER ViscosityVery low to MiddleVery low to MiddleHighMiddleMiddle Storage stabilityExcellentExcellent ?Modest or PoorPoorPoor? Capacity of production methodWide (from hot to cold process)Only cold process with silane?Only cold process with silaneOnly cold process with silaneOnly cold process with

45、 silane?Sealant / Adhesive Curing speedFast to MiddleFastFastFastFast Modulus / HardnessLow to HighLow to HighMiddle to HighMiddle to HighLow? to High ElasticityExcellentGood (Brittle)?Good (Brittle)Good (Brittle)Good (Brittle)? StrengthMiddle or high (SAX700s)Middle Middle (higher than MS ?)Middle(

46、higher than MS ?)Middle? Storage stabilityExcellentExcellentGood Good Good RecoveryBadGood (ISO/SNJF)?Good (ISO/SNJF)Good (ISO/SNJF)Bad ? Adhesive propertyExcellentExcellentGood or PoorGood or PoorGood or Poor UV resistanceGood or excellent (MAX)Good or excellent (MAX)?Modest or goodGoodGood Heat re

47、sistanceGoodGood?Modest or goodGoodGood Tin regulationModest ( 0.5%)Good (less tin)Good (less tin)Good (less tin)Excellent (non tin)“雪亮工程是以区（县）、乡（镇）、村（社区）三级综治中心为指挥平台、以综治信息化为支撑、以网格化管理为基础、以公共安全视频监控联网应用为重点的“群众性治安防控工程”。Heat Resistance at 90C90C0 . 00 . 20 . 40 . 60 . 81 . 01 . 21 . 4M 1 0 0 (M Pa)M S -1

48、M S -2PU -1S i PU -1S i PU -2S i PU -3I ni ti alA fter 4 W“雪亮工程是以区（县）、乡（镇）、村（社区）三级综治中心为指挥平台、以综治信息化为支撑、以网格化管理为基础、以公共安全视频监控联网应用为重点的“群众性治安防控工程”。Table 1 HENKEL POWER FIX (Wit-Blanc) - tested at Oligomer lab.HENKELSOUDALSOUDALPOWER FIX(Wit-Blanc)FIX ALLFIX ALLHigh Tack71764436639657639642Pale cream - whi

49、teWhiteWhiteISPUPPG16000S303H?S303H?ca. 25wt%?1008001100Curing speedSFT(min)2420429(23C-50%RH)TFT(min)2595-10913Hardness after 1d281522(Shore A)after 3d493748(23C-50%RH)after 7d504852Cure in depthafter 1d2,82,42,1(23C-50%RH)after 7d6,26,75,5Residual tackafter 1d444(23C-50%RH)after 3d555after 7d555Te

50、nsile propertyM50 / MPa1,150,711,52by dumbbell shapeM100 / MPa1,580,992,01(23C-50%)*3dTB / MPa2,421,772,57+ 50C*4dEB / %350720250Viscosity1 rpm504056407632(23C-50%)2 rpm29103186427810 rpm9068651157(2 rpm/10 rpm)3,23,73,7Adhesion propertyglassC100C100C10090C hand-peelanodized AlC100C100C100DRYstainle